By Irina A. Maretina,Boris I. Ionin
Acetylene structures current a brand new path to cyclic compounds in its place to more conventional equipment hired in classical natural chemistry. The synthesis of cyclic buildings in line with acetylene structures has vital purposes within the formation of nanostructures, obviously taking place compounds and chemosensory fabrics for the layout of nonlinear optics, digital and photonic devices.
Alkynes in Cycloadditions offers a contemporary assessment of regioselective synthesis of fragrant and non-aromatic carbocyclic and heterocyclic ring structures established totally on [2+2+2] and [4+2] cycloadditions, and different reactions of acetylenic devices together with enediynes and enyne-allenes.
Topics lined include:
- New suggestions for the formation of fragrant and polynuclear hydrocarbons according to (Z)-hex-3-en-1,5-diyne and (Z)-hepta-1,2,4-triene-6-yne blocks.
- One-step synthesis of benzene derivatives, β-substituted naphthalenes and acenes through the cycloaromatization of enediynes and enyne-allenes by means of Bergman, Myers-Saito and Shmittel.
- Mechanisms of cycloaromatization leading to the formation of fulvene and indene systems.
- Heterocyclization related to enyne-carbodiimides.
- New achievements in classical cycloaddition reactions comparable to the Diels-Alder condensation with acetylenic dienophiles and [2+2] cycloadditions with acetylene components
Alkynes in Cycloadditions provides a finished precis of the literature on equipment for the synthesis of ring platforms from acetylenes for tutorial researchers operating within the fields of natural synthesis, actual natural chemistry, organometallic chemistry, catalysis, fabrics technology, nanomaterials and biochemistry.
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